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Neuigkeiten aus dem Arbeitskreis 2008

 


Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation:

C. Strohmann, V. H. Gessner, J. Am. Chem. Soc. 2008, 130, 14412-14413, DOI: 10.1021/ja8058205

 

2008_Strohmann_JACS_14412

 


A Precoordination Complex of 1,2,3-Trimethyl-1,3,5-triazacyclohexane with tert-Butyllithium as Key Intermediate in Its Methylene Group Deprotonation

C. Strohmann, V.H. Gessner, Chem. Asian J. 2008, 3, 1929-1934, DOI: 10.1002/asia.200800213

 

2008_Strohmann_Chem.AsianJ._1929

 


iso-Propyllithium Diamine Adducts: From a Non Symmetric Aggregate to Monomeric iPrLi·(1R,2R)-N,N,N',N'-Tetraethylcyclohexane-1,2-diamine:

C. Strohmann, V.H. Gessner, A. Damme, Chem. Commun. 2008, 3381-3383, DOI: 10.1039/B804855J

 

2008_Strohmann_Chem.Commun._3381

 


Structure/Reactivity Studies on an α-Lithiated Benzyl Silane: Chemical Interpretation of Experimental Charge Density:

H. Ott, C. Däschlein, D. Leusser, D. Schildbach, T. Seibel, D. Stalke, C. Strohmann, J. Am. Chem. Soc. 2008, 130, 11901-11911, DOI: 10.1021/ja711104q

 

2008_Ott-JACS_11901

 


Bent Phenyl Groups in Lithiosilanes – Crystal Structures and Interpretation of this Unanticipated Feature:

C. Strohmann, C. Däschlein, Chem. Commun. 2008, 2791-2793, DOI: 10.1039/B802211A

 

2008_Strohmann_Chem.Commun._2791

 


Synthesis and Reactivity of Silylated Tetrathiafulvalenes:

A. Hameau, F. Guyon, M. Knorr, C. Däschlein, C. Strohmann,  N. Avarvari, Dalton Trans. 2008, 4866-4876, DOI: 10.1039/B803947J

 

2008_Hameau_DaltonTrans._4866

 


Crystal Structures of n-BuLi Adducts with (R,R)-TMCDA and the Consequences for the Deprotonation of Benzene:

C. Strohmann, V. H. Gessner, J. Am. Chem. Soc. 2008, 130, 11719-11725, DOI: 10.1021/ja8017187

2008_Strohmann_JACS_11719

 

 


Synthesis of a highly enantiomerically enriched Silagermane and Selective Cleavage of the Si–Ge Bond with Lithium:

C. Strohmann, C. Däschlein, Organometallics 200827, 2499-2504, DOI: 10.1021/om700848z

 

2008_Strohmann_Organometallics_2499

 


 

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